Material safety data sheet

Click Bond - CB200 Adhesive - Material Safety Data Sheet
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: CB200 Product
ADHESIVE
CLICK BOND, INC. INFORMATION TELEPHONE #: (775) 885-8000 2151 LOCKHEED WAY EMERGENCY TELEPHONE #: (800) 255-3924 (CHEM•TEL) CARSON CITY, NV 89706 OUTSIDE NORTH AMERICA #: (813) 248-0585 CALL COLLECT SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Component Chemical Name Less Than TLV-TWA TLV-STEL PEL-TWA PEL-Ceiling Methyl methacrylate ppm N.E. N.E. N.E. Methacrylate phosphate ester Proprietary 5% N.E. N.E. N.E. N.E. N,N-Dimethylaniline Proprietary 5% N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.A. – Not Applicable, N.E. - Not Established, S - Skin Designation SECTION 3 - HAZARDS IDENTIFICATION
*** EMERGENCY OVERVIEW ***: Off-white Liquid, with Sweet odor (Component B) and Yellow Paste, with No odor
(Component A). Flammable liquid. Harmful if absorbed through skin. May cause allergic skin reaction. Causes skin and eye
irritation. Causes respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May be absorbed through the skin in harmful amounts. Causes
skin irritation. May cause skin sensitization. May cause dermatitis.
EFFECTS OF OVEREXPOSURE - INHALATION: Causes respiratory tract irritation. May cause headache and nausea.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Ingestion is not an expected route of entry in
industrial or commercial uses.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause liver or kidney damage. Chronic skin contact
may cause dermatitis.
PRIMARY ROUTE (S) OF ENTRY: Skin Contact, Skin Absorption, Inhalation, Ingestion, Eye Contact
SECTION 4 - FIRST AID MEASURES
FIRST AID - EYE CONTACT: Flush eyes immediately with large amount of water for at least 15 minutes holding eyelids
open while flushing. Get prompt medical attention.
FIRST AID - SKIN CONTACT: Flush contaminated skin with large amounts of water while removing contaminated
clothing. Wash affected skin areas with soap and water. Get medical attention if symptoms occur.
FIRST AID - INHALATION: Move person to fresh air. Restore and support continued breathing. If breathing is difficult,
give oxygen. Get immediate medical attention.
FIRST AID - INGESTION: If swallowed, do not induce vomiting. Give victim one or two glasses of water or milk. Call a
physician or poison control center immediately for further instructions. Never give anything by mouth if victim is rapidly
losing consciousness, unconscious or convulsing.
SECTION 5 - FIRE-FIGHTING MEASURES
Component A:
FLASH POINT: 201 Deg. F, 93 Deg. C (Setaflash Closed Cup)
LOWER EXPLOSIVE LIMIT (%): Not
AUTOIGNITION TEMPERATURE: N.D.
UPPER EXPLOSIVE LIMIT (%): Not
Component B:
FLASH POINT: 65 Deg. F, 18 Deg. C (Setaflash Closed Cup)
LOWER EXPLOSIVE LIMIT (%): 1.0%
AUTOIGNITION TEMPERATURE: N.D.
UPPER EXPLOSIVE LIMIT (%): 8.8%
Page 1 of 3 - 9NOV08 - Click Bond CB200 MSDS Rev. 5
SECTION 5 - FIRE-FIGHTING MEASURES (Cont.)
Components A and B:
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable liquid and vapor. Keep containers tightly closed. Isolate
from heat, electrical equipment, sparks, open flame, and other sources of ignition. Closed containers may rupture when
exposed to extreme heat. Use water spray to keep fire exposed containers cool. During a fire, irritating and/or toxic gases and
particulate may be generated by thermal decomposition or combustion.
SPECIAL FIREFIGHTING PROCEDURES: Wear full firefighting protective clothing, including self-contained
breathing apparatus (SCBA). If water is used, fog nozzles are preferable.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Keep non-essential personnel a safe
distance away from the spill area. Remove all sources of ignition (flame, hot surfaces, and electrical, static, or frictional
sparks). Avoid breathing vapors. Use self-contained breathing equipment. Notify appropriate authorities if necessary. Avoid
contact. Using non-sparking tools, scoop the spilled material into an appropriate container for proper disposal. (If necessary,
use inert absorbent material to aid in containing the spill.)
SECTION 7 - HANDLING AND STORAGE
HANDLING: Keep closure tight and container upright to prevent leakage. Ground and bond containers when transferring
material. Avoid skin and eye contact. Wash thoroughly after handling. Avoid breathing of vapor or spray mists. Do not
handle until all safety precautions have been read and understood. Use with adequate ventilation. Because empty containers
may retain product residue and flammable vapors, keep away from heat, sparks, and flame; do not cut, puncture, or weld on
or near the empty container. Empty containers should not be re-used. Do not smoke where this product is used or stored.
STORAGE: Refer to OSHA 29CFR Part 1910.106 "Flammable and Combustible Liquids" for specific storage requirements.
Store only in well-ventilated areas. Keep container closed when not in use.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Sufficient ventilation in pattern and volume should be provided in order to maintain air
contaminant levels below recommended exposure limits. Sufficient ventilation (using explosion-proof equipment) should be
provided to prevent flammable vapor/air mixtures from accumulating.
RESPIRATORY PROTECTION: Contains a small amount of dimethylaniline (DMA) which has poor odor-warning
properties. If the exposure limit for DMA is exceeded, an air-supplied respirator is recommended. Otherwise, a properly-
fitted NIOSH approved air-purifying organic vapor respirator is recommended. For emergency situations, confined space
use, or other conditions where exposure limits may be greatly exceeded, use an approved air-supplied respirator. Observe
OSHA regulations (29CFR 1910.134) for respirator use.
SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact.
EYE PROTECTION: Use safety eyewear including safety glasses with side shields and chemical goggles where splashing
may occur.
OTHER PROTECTIVE EQUIPMENT: Use disposable or impervious clothing if work clothing contamination is likely.
Remove and wash contaminated clothing before reuse.
HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Food or beverages should not be
consumed anywhere this product is handled or stored. Wash thoroughly after handling.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Component A:
BOILING RANGE
: 212 – 212 Deg. F
DENSITY, LB/GAL
APPEARANCE : Yellow
FREEZE POINT
VOLATILE BY WEIGHT : 5.49% PHYSICAL STATE
SOLUBILITY IN H2O : Insoluble
VOLATILE BY VOLUME : 6.71% ODOR : No
VAPOR DENSITY
: Heavier than Air
VAPOR PRESSURE
ODOR THRESHOLD : N.D.
EVAPORATION RATE : N.A.
COEFFICIENT OF WATER/OIL DISTRIBUTION: N.D.
(See Section 16 for abbreviation legend.) Component B:
BOILING RANGE
: 214 – 379 Deg. F
DENSITY, LB/GAL
APPEARANCE : Off-white
FREEZE POINT
VOLATILE BY WEIGHT : 0.0%
PHYSICAL STATE
SOLUBILITY IN H2O : Insoluble
VOLATILE BY VOLUME : 0.0%
ODOR : Sweet
VAPOR DENSITY
: Heavier than Air
VAPOR PRESSURE
ODOR THRESHOLD : N.D.
EVAPORATION RATE : Faster than n-butyl-acetate
COEFFICIENT OF WATER/OIL DISTRIBUTION: N.D.
(See Section 16 for abbreviation legend.) Page 2 of 3 - 9NOV08 - Click Bond CB200 MSDS Rev. 5
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Storage above 100 degrees F and below 32 degrees F. Exposure to sunlight, ultraviolet light
irradiation. Avoid dropping or puncture of containers.
INCOMPATIBILITY: Inorganic acids, organic acids, caustics, amines, oxidizing agents, peroxides, water, hydroxyl, or
active hydrogen compounds.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, oxides of nitrogen, aldehydes.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur under normal conditions.
STABILITY: Product is stable under normal storage conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
PRODUCT LD50 (ORAL): No data
PRODUCT LD50 (DERMAL): No data
PRODUCT LC50: No data
SECTION 12 - ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: No information
SECTION 13 - DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Disposal should be done in accordance with Federal (40CFR Part 261), state, and local
environmental control regulations. If waste is determined to be hazardous, use licensed hazardous waste transporter and
disposal facility.
SECTION 14 - TRANSPORTATION INFORMATION
DOT PROPER SHIPPING NAME: Adhesives
DOT HAZARD CLASS: 3 DOT UN/NA NUMBER: 1133
EMERGENCY RESPONSE GUIDE NUMBER: 128
PACKING GROUP: II
SECONDARY HAZARD: None
The listed transportation classification applies to US DOT non-bulk road shipments. It does not address regulatory variations due to changes in package size, mode of shipment or other regulatory descriptors. For the most accurate shipping information, refer to your transportation/compliance department. SECTION 15 - REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
This product is considered hazardous as defined by 29 CFR 1910.1200 (OSHA HazCom Standard).
SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372:
Chemical Name
CAS Number
Weight % Less Than
Methyl methacrylate N,N-Dimethylaniline Benzoyl peroxide TOXIC SUBSTANCES CONTROL ACT:
INVENTORY STATUS: The chemical substances in this product are on the TSCA Section 8 Inventory.
EXPORT NOTIFICATION: This product contains the following chemical substances subject to the reporting requirements
of TSCA 12(B) if exported from the United States:
SECTION 16 - OTHER INFORMATION
HMIS RATINGS - HEALTH: 2*
PHYSICAL HAZARD: 2 * - Indicates a chronic hazard; see Section 3. VOLATILE ORGANIC COMPOUNDS
0.0 lbs/gal, 0.0 grams/liter NOTE: In normal use, the acrylate monomer in this product is considered to be non-volatile and is polymerized during cure. For purposes of air quality regulations, the maximum amount of VOC emitted is less than 5%. Actual emissions are a function of processing conditions. LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
DISCLAIMER: The information contained herein is, to the best of our knowledge and belief, accurate. However, since the
conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages
incurred by use of this material. It is the responsibility of the user to comply with all applicable federal, state, and local laws
and regulations.
Page 3 of 3 - 9NOV08 - Click Bond CB200 MSDS Rev. 5

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